Smith教授等编著的《化工热力学导论》是世界化工领域影响最大、发行范围最广的化工热力学教材。本书是根据英文原版书《化工热力学导论》第7版改编。
改编书选取了原书前13章，内容涵盖了化学工程师专业教育所必需的内容。全书主要内容包括以下几个方面：热力学基本概念和基本定律、纯流体的PVT性质、热效应、纯流体的热力学性质、热力学在流动过程中的应用、热力做功、制冷、汽液平衡、溶液热力学理论和应用以及化学反应平衡。这13章内容可以分为三部分：热力学和化学热力学基础，包括第1-6章；热力学在工业过程中的应用，包括第7-9章；热力学在化学过程中的应用，包括第10-13章。书中给出了大量既有理论意义，又切合工业实际的例题，并配有大量来自工业实践的习题。
全书行文流畅、图表丰富、通俗易懂。可作为化学工程与工艺专业以及其他相关专业的化工热力学教科书，也可以作为相关专业研究人员，工程设计和生产管理技术人员的重要参考书，也可以用作化工专业英语的教材或选读材料。
江振西，ZhenxiJiang，郑州大学教授。1954年7月生于河北省磁县。1975年入郑州工学院（现郑州大学）化工系就读无机化工专业。1978年考入新乡师范学院（现河南师范大学）化学系物理化学专业。1981年毕业于新乡师范学院，获研究生毕业证书，1982年获武汉大学理学硕士学位。1982年3月起在郑州工学院任教，主教化工热力学等课程。1989年获中国政府、包玉刚基金会和英国政府共同设立的中英友好奖学金赴英国利兹大学访问研究。1990年获英国海外留学生奖学金和利兹大学Tetley and Lupton 奖学金读博士学位，1994年获利兹大学哲学博士学位。之后继续在利兹大学从事研究工作。2006年开始，在郑州大学教授化工热力学（双语）课程、研究生专业英语和研究生高等化工热力学（全英语）等课程。
List of Symbols
Preface
Chapter 1 Introduction1
1.1 THE SCOPE OF THERMODYNAMICS1
1.2 DIMENSIONS AND UNITS2
1.3 MEASURES OF AMOUNT OR SIZE2
1.4 FORCE3
1.5 TEMPERATURE4
1.6 PRESSURE6
1.7 WORK8
1.8 ENERGY9
1.9 HEAT14
KEY NOTES15
GLOSSARY AND EXPLANATIONS17 List of Symbols
Preface
Chapter 1 Introduction1
1.1 THE SCOPE OF THERMODYNAMICS1
1.2 DIMENSIONS AND UNITS2
1.3 MEASURES OF AMOUNT OR SIZE2
1.4 FORCE3
1.5 TEMPERATURE4
1.6 PRESSURE6
1.7 WORK8
1.8 ENERGY9
1.9 HEAT14
KEY NOTES15
GLOSSARY AND EXPLANATIONS17
CONCEPTUAL PROBLEMS27
PROBLEMS28
Chapter 2 The First Law and Other Basic Concepts33
2.1 JOULE’S EXPERIMENTS33
2.2 INTERNAL ENERGY33
2.3 THE FIRST LAW OF THERMODYNAMICS34
2.4 ENERGY BALANCE FOR CLOSED SYSTEMS35
2.5 THERMODYNAMIC STATE AND STATE FUNCTIONS37
2.6 EQUILIBRIUM40
2.7 THE PHASE RULE41
2.8 THE REVERSIBLE PROCESS43
2.9 CONSTANT-V AND CONSTANT-P PROCESSES48
2.10 ENTHALPY49
2.11 HEAT CAPACITY51
2.12 MASS AND ENERGY BALANCES FOR OPEN SYSTEMS55
KEY NOTES65
GLOSSARY AND EXPLANATIONS68
CONCEPTUAL PROBLEMS84
PROBLEMS85
Chapter 3 Volumetric Properties of Pure Fluids93
3.1 PVT BEHAVIOR OF PURE SUBSTANCES93
3.2 VIRIAL EQUATIONS OF STATE98
3.3 THE IDEAL GAS101
3.4 APPLICATION OF THE VIRIAL EQUATIONS113
3.5 CUBIC EQUATIONS OF STATE117
3.6 GENERALIZED CORRELATIONS FOR GASES126
3.7 GENERALIZED CORRELATIONS FOR LIQUIDS134
KEY NOTES136
GLOSSARY AND EXPLAINATIONS140
CONCEPTUAL PROBLEMS147
PROBLEMS149
Chapter 4 Heat Effects162
4.1 SENSIBLE HEAT EFFECTS162
4.2 LATENT HEATS OF PURE SUBSTANCES169
4.3 STANDARD HEAT OF REACTION171
4.4 STANDARD HEAT OF FORMATION173
4.5 STANDARD HEAT OF COMBUSTION176
4.6 TEMPERATURE DEPENDENCE OF ΔH 176
4.7 HEAT EFFECTS OF INDUSTRIAL REACTIONS179
KEY NOTES187
GLOSSARY AND EXPLAINATIONS187
CONCEPTUAL PROBLEMS193
PROBLEMS194
Chapter 5 The Second Law of Thermodynamics202
5.1 STATEMENTS OF THE SECOND LAW202
5.2 HEAT ENGINES203
5.3 THERMODYNAMIC TEMPERATURE SCALES206
5.4 ENTROPY209
5.5 ENTROPY CHANGES OF AN IDEAL GAS212
5.6 MATHEMATICAL STATEMENT OF THE SECOND LAW215
5.7 ENTROPY BALANCE FOR OPEN SYSTEMS217
5.8 CALCULATION OF IDEAL WORK222
5.9 LOST WORK226
5.10 THE THIRD LAW OF THERMODYNAMICS229
KEY NOTES230
GLOSSARY AND EXPLAINATIONS231
CONCEPTUAL PROBLEMS237
PROBLEMS239
Chapter 6 Thermodynamic Properties of Fluids247
6.1 PROPERTY RELATIONS FOR HOMOGENEOUS PHASES247
6.2 RESIDUAL PROPERTIES256
6.3 RESIDUAL PROPERTIES BY EQUATIONS OF STATE263
6.4 TWO-PHASE SYSTEMS268
6.5 THERMODYNAMIC DIAGRAMS273
6.6 TABLES OF THERMODYNAMIC PROPERTIES274
6.7 GENERALIZED PROPERTY CORRELATIONS FOR GASES278
KEY NOTES287
GLOSSARY AND EXPLAINATIONS288
CONCEPTUAL PROBLEMS293
PROBLEMS295
Chapter 7 Applications of Thermodynamics to Flow Processes308
7.1 DUCT FLOW OF COMPRESSIBLE FLUIDS309
7.2 TURBINES (EXPANDERS)321
7.3 COMPRESSION PROCESSES327
KEY NOTES333
GLOSSARY AND EXPLAINATIONS335
CONCEPTUAL PROBLEMS340
PROBLEMS342
Chapter 8 Production of Power from Heat352
8.1 THE STEAM POWER PLANT353
8.2 INTERNAL-COMBUSTION ENGINES363
8.3 JET ENGINES，ROCKET ENGINES AND RAMJET ENGINES371
KEY NOTES373
GLOSSARY AND EXPLAINATIONS374
CONCEPTUAL PROBLEMS377
PROBLEMS379
Chapter 9 Refrigeration and Liquefaction384
9.1 THE CARNOT REFRIGERATOR384
9.2 THE VAPOR-COMPRESSION CYCLE385
9.3 THE CHOICE OF REFRIGERANT388
9.4 ABSORPTION REFRIGERATION390
9.5 THE HEAT PUMP392
9.6 LIQUEFACTION PROCESSES393
KEY NOTES398
GLOSSARY AND EXPLAINATIONS399
CONCEPTUAL PROBLEMS403
PROBLEMS404
Chapter 10 Vapor/Liquid Equilibrium: Introduction409
10.1 THE NATURE OF EQUILIBRIUM409
10.2 THE PHASE RULE; DUHEM’S THEOREM410
10.3 VLE: QUALITATIVE BEHAVIOR412
10.4 SIMPLE MODELS FOR VAPOR/LIQUID EQUILIBRIUM414
10.5 VLE BY MODIFIED RAOULT’S LAW423
10.6 VLE FROM K-VALUE CORRELATIONS428
KEY NOTES434
GLOSSARY AND EXPLAINATIONS435
CONCEPTUAL PROBLEMS442
PROBLEMS444
Chapter 11 Solution Thermodynamics: Theory452
11.1 FUNDAMENTAL PROPERTY RELATION452
11.2 THE CHEMICAL POTENTIAL AND PHASE EQUILIBRIA454
11.3 PARTIAL PROPERTIES455
11.4 THE IDEAL-GAS MIXTURE MODEL466
11.5 FUGACITY AND FUGACITY COEFFICIENT: PURE SPECIES469
11.6 FUGACITY AND FUGACITY COEFFICIENT: SPECIES IN SOLUTION475
11.7 GENERALIZED CORRELATIONS FOR THE FUGACITY COEFFICIENT481
11.8 THE IDEAL-SOLUTION MODEL485
11.9 EXCESS PROPERTIES487
KEY NOTES493
GLOSSARY AND EXPLAINATIONS496
CONCEPTUAL PROBLEMS501
PROBLEMS502
Chapter 12 Solution Thermodynamics: Applications512
12.1 LIQUID-PHASE PROPERTIES FROM VLE DATA512
12.2 MODELS FOR THE EXCESS GIBBS ENERGY527
12.3 PROPERTY CHANGES OF MIXING530
12.4 HEAT EFFECTS OF MIXING PROCESSES536
KEY NOTES548
GLOSSARY AND EXPLAINATIONS549
CONCEPTUAL PROBLEMS553
PROBLEMS555
Chapter 13 Chemical-Reaction Equilibria567
13.1 THE REACTION COORDINATE568
13.2 APPLICATION OF EQUILIBRIUM CRITERIA TO CHEMICAL REACTIONS572
13.3 THE STANDARD GIBBS-ENERGY CHANGE AND THE EQUILIBRIUM
CONSTANT573
13.4 EFFECT OF TEMPERATURE ON THE EQUILIBRIUM CONSTANT575
13.5 EVALUATION OF EQUILIBRIUM CONSTANTS579
13.6 RELATION OF EQUILIBRIUM CONSTANTS TO COMPOSITION581
13.7 EQUILIBRIUM CONVERSIONS FOR SINGLE REACTIONS585
13.8 PHASE RULE AND DUHEM’S THEOREM FOR REACTING SYSTEMS597
13.9 MULTIREACTION EQUILIBRIA601
KEY NOTES611
GLOSSARY AND EXPLAINATION613
CONCEPTUAL PROBLEMS617
PROBLEMS619
Appendix A Conversion Factors and Values of the Gas Constant630
Appendix B Properties of Pure Species632
Appendix C Heat Capacities ad Property Changes of Formation636
Appendix D Representative Computer Programs641
参考文献651
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